Advanced Organic Chemistry Practice Problems 2021 [Simple]

for the following reaction and provide a detailed arrow-pushing mechanism. -3-methylcyclohexanone cap L cap D cap A cap C cap H sub 3 cap I What is the stereochemical outcome at the Solution Approach: Enolate Formation: cap L cap D cap A

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The phosphate binds the isoquinolinium ion via H-bonding and π-stacking, shielding one enantioface. At higher T, the ion pair dissociates partially, reducing stereoinduction. At higher T, the ion pair dissociates partially,

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